However, its still sugar, so consume it sparingly. Plant seeds also produce enzymes to release sugar from starch as they sprout. In the case of disaccharides, one monosaccharide acts a the hemiacetalwhile the other monosaccharides acts as the alcohol. At the same time, intestinal bacteria may act on the lactose to produce organic acids and gases. . Monosaccharides can be further classified by the number of 2023 Healthline Media LLC. It is important as an infant food and in the production of penicillin. Organic Chemistry Study Materials, Practice Problems, Summary Sheet Guides, Multiple-Choice Quizzes. Lactose is a disaccharide consisting of glucose and galactose and is found naturally in milk. He holds a Master's of Science from the Central University of Punjab, India. This done for the D isomers since these are the naturally occurring sugars. So, for a carbohydrate to be an aldoseit needs an aldehydegroup. Aldoses can tautomerize to ketoses in a dynamic process with an enol intermediate (more specifically, an enediol). This is . In the body, such hydrolysis reactions are catalyzed by enzymes such as maltase. These individuals are said to be lactose intolerant because they cannot digest the lactose found in milk. People commonly use sucrose, also known as table sugar, for cooking and sweetening foods. Sometimes called the hot dog of the sea, imitation crab is a popular ingredient in dishes like seafood salads, crab cakes or California sushi rolls, Protein is essential for building and maintaining muscle mass but consuming too much can negatively affect your health. An example of this reaction is found in germinating seeds, which is why it was named after malt. We found that Daily One Supplements contained reducing sugars, hexose-pyranoses, and starch while Flintstones contained hexose-furanoses and both monosaccaride and disaccharide ketoses. The incidence of galactosemia in the United States is 1 in every 65,000 newborn babies. The determination is made based on the chirality of the asymmetric carbon furthest from the aldehyde end, namely the second-last carbon in the chain. C) the position of the carbonyl group. The molecular weight of reducing sugars is relatively high when compared to that of reducing sugars. Lactose, or milk sugar, is a disaccharide found in milk. All About Raw Honey: How Is It Different Than Regular Honey? In the manufacture of jelly and candy and in the canning of fruit, the recrystallization of sugar is undesirable. Despite these differences, aldoses and ketoses are very similar compounds and can easily be interconverted. Sugars include, glucose, galactose, fructose, maltose, lactose The dark brown liquid that remains after the recrystallization of sugar is sold as molasses. Who are the experts? Maltose is an intermediate sugar form by the action of amylase catalyzed hydrolysis of starch. The simplest of the carbohydrates, i.e., monosaccharides, as well as disaccharides (compounds made up of two monosaccharide units), is most commonly referred to as simple sugars. Both are polyhydroxy alcohols, but one is an aldehyde and the other a ketone. Some of the commonly found ketoses in nature and around us include: Just like aldoses, the most common way of depicting the chemical structures of ketoses is to use Fischer projection formulae. Lets start with aldotereoses. Products of oxidation of aldoses The aldehyde functional group of aldoses can be oxidized to carboxyl groups under the action of mild oxidants, forming aldonic acids. Answered: The difference between an aldose sugar | bartleby Aldoses can also tautomerize into ketoses through the dynamic process with an enol intermediate formation. Sucrose is not considered an aldose or a ketose, because it is a disaccharide made from glucose (an aldose) and fructose (a ketose). An aldose is a monosaccharide that contains an aldehydic functional group as its main functional group, while a ketose contains the ketonic functional group as its main functional group. Therefore, an ingested disaccharide must first be broken down by hydrolysis into its two constituent monosaccharide units. As a result, many adults experience a reduction in the ability to hydrolyze lactose to galactose and glucose in their small intestine. Some aldohexoses that are widely called by common names are:[4]. When the anomeric carbon on both monosaccharides is involved in the formation of the glycosidic bond, the disaccharides is non-reducing. Based on Greek number terms, hexose indicates six carbons and pentose implies five carbons. All aldoses exhibit stereoisomerism as they have an asymmetrical carbon center. Non-reducing sugars give a negative reaction towards the Fehling's test. Its all here Just keep browsing. 14.2: Classes of Monosaccharides - Chemistry LibreTexts Fructose is, thus, an example of a (n): a) aldopentose b) ketoheptose c) aldohexose d) aldotetrose e) ketohexose. If it is a reducing sugar, draw its structure and circle the anomeric carbon. Aldoses can be distinguished from ketoses based on the ability of Bromine to oxidize aldehydic groups but not ketonic functional groups. Also, they are mostly found in grains and cereals. All three are white crystalline solids at room temperature and are soluble in water. [10], Outside of plants, maltose is also (likely) found in sugarbag. and all polysaccharides are in this group. Thus, ketoses have the same general formula as the aldoses, i.e., {eq}(C_{n}H_{2n}O_{n}) {/eq} where n represents the number of carbon atoms making up the backbone. It is useful in making hard candies and an inexpensive sweetener. Nutritionally, maltose provides the same number of calories as starches and other sugars. Aldoses with alcohol groups on the right of the Fischer projection are D-aldoses, and those with alcohols on the left are L-aldoses. This linkage is formed from the reaction of the anomeric carbon of one cyclic monosaccharide with the OH group of a second monosaccharide. Maltose can be broken down to glucose by the maltase enzyme, which catalyses the hydrolysis of the glycosidic bond. Thus, foods like. Disaccharidescan be reducing or non-reducing, depending on the specific groups involved in the formation of the glycosidic bond. Chapter 18, Problem 52EP is solved. Next, the aldehydic functional group is attached to a carbon atom at either end of the backbone. Up to 20% of the US population suffers some degree of lactose intolerance. Bromine, which is red in color, becomes colorless when it is reduced (which happens only in the presence of aldoses). Maltose is made of two glucose units. The hydroxyl group attached to the carbon atom at one end of the backbone is called a primary alcohol group, while the rest of the hydroxyl groups are called secondary alcohol groups. You can use maltose in recipes as a 1:1 substitute for other sugars. Is Sucrose an Aldose? | Sciencing The difference between an aldose sugar and a ketose sugar is ________. Thanks to growing public awareness about the negative health effects of high-fructose corn syrup and other sweeteners containing fructose, many food companies are switching to maltose, which contains no fructose. For some people the inability to synthesize sufficient enzyme increases with age. The disease may result in impaired liver function, cataracts, mental retardation, and even death. Seliwanoff's test is a chemical test which differentiates between Aldose and ketose sugars. There are many vegan protein powders on the market, with a variety of flavors and ingredients available. An infant with galactosemia experiences a lack of appetite, weight loss, diarrhea, and jaundice. Maltose can be purchased as dry crystals where brewing supplies are sold or as a syrup sold alongside baking supplies. Thus, foods like cereals, certain fruits and sweet potatoes contain naturally high amounts of this sugar. One of the most common ways is to use Fischer projection formulas, first used by the Nobel prize-winning German chemist Emil Fischer. Experiment: Molisch's test: 1 ml lactose/maltose + 2 or 3 drops of Molisch's reagent. Sucrose The OH group on the anomeric carbon of the second glucose can be in either the or the position, as shown in Figure 1. Hexoses (6-carbons) are by far the most prevalent. Therefore, conditions leading to the hydrolysis of sucrose are employed in these processes. But actually, their fructose content is very similar. Fructose, ribulose, dihydroxyacetone are some of the examples of ketoses. It is a non . Aldoses are a type of monosaccharides that contain the aldehydic functional group (a type of carbonyl functional group) as the main functional group attached to the carbon chain(backbone) of the compound. This article addresses how maltose affects your body, where it comes from and whether its healthy or unhealthy. Yields two to ten monosaccharides. Malted grains are also used in candies and desserts as sweeteners. For an aldose, the basic structure involves drawing a carbon backbone with each carbon attached to its adjacent carbon atom via a single bond. Like aldoses, ketoses also have a backbone made up of carbon atoms bonded via a single covalent bond. { "2.01:_Introduction" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "2.02:_Classification_of_Carbohydrates" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "2.03:_Fischer_Projections" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "2.04:_D_and_L_Monosaccharides" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "2.05:_Physical_properties_of_monosaccharides" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "2.06:_Cyclic_Structures_of_Monosaccharides" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "2.07:_Reactions_of_Monosaccharides" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "2.08:_Important_Hexoses" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "2.09:_Disaccharides_and_Glycosidic_Bonds" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "2.10:_Polysaccharides" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "2.11:_Other_Important_Carbohydrates" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "2.12:_Cell_Surface_Carbohydrates_and_Influenza_Viruses" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()" }, { "00:_Front_Matter" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "01:_Intro_to_Biochem" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "02:_Carbohydrates" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "03:_Lipids" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "04:_Amino_Acids_and_Proteins" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "05:_Enzymes" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "06:_Nucleic_Acids" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "07:_Nutrition" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "08:_Metabolism_of_carbohydrates" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "09:_Metabolism_of_Lipids" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "10:_Metabolism_of_Amino_Acids" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "zz:_Back_Matter" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()" }, [ "article:topic", "hypothesis:yes", "showtoc:no", "source[1]-chem-45987", "source[2]-chem-45987" ], https://chem.libretexts.org/@app/auth/3/login?returnto=https%3A%2F%2Fchem.libretexts.org%2FCourses%2FBrevard_College%2FCHE_301_Biochemistry%2F02%253A_Carbohydrates%2F2.09%253A_Disaccharides_and_Glycosidic_Bonds, \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}}}\) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash{#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\). To Your Health: Lactose Intolerance and Galactosemia. Aldoses can exist in a cyclic form called hemiacetals. If we compare the osazone formation of glucose (aldose) and fructose (ketose) we observe that both utilized the three equivalents of the reagent but the product contains the two phenyl hydrazine residues. Fructose is a simple hexose sugar commonly found in plants and is one of the three dietary monosaccharides along with glucose and galactose. . Alternatively, many food stores now carry special brands of milk that have been pretreated with lactase to hydrolyze the lactose. C) they differ in length by one carbon. Remember that an aldehyde group, here shown as CH=O, is also often written as CHO. As mentioned in the picture, D and L isomers are enantiomers and any other pair represents diastereomers. Glucose, fructose, galactose, ribose, arabinose, sucrose, maltose, lactose, DHA, erythrulose, tagatose, psicose are some of the important monosaccharides that we encounter daily in both, natural and processed foods. \[\mathrm{maltose \xrightarrow{H^+\: or\: maltase} \textrm{2 D-glucose}} \]. Epimers in Chemistry: Concept & Examples | What are Epimers? ?On the transformation-products of starch", "150 Years Alfred Whlk:: Education:: ChemistryViews", https://en.wikipedia.org/w/index.php?title=Maltose&oldid=1149457132, 160 to 165C (320 to 329F; 433 to 438K) (anhydrous), This page was last edited on 12 April 2023, at 10:54. Is Lactose an Aldose? | Healthfully These are the two pairs of enantiomers of threose and erythrose. The carbon atoms in ketoses are asymmetrical, resulting in different forms of sugars due to the chirality of the asymmetrical carbon. In the isomer isomaltose, the two glucose molecules are joined with an (16) bond. How many aldose, ketose, furanose, pyranose and hemiactel - Brainly Simple carbohydrates: one to three units of sugar linked together. These, in turn, generate four possible aldopentoses and then aldohexoses: Two main differences between aldoses and ketoses: 1) ketoses contain a ketone rather than an aldehyde C=O. The cyclic ketoses are termed hemiketals. Cooking or fermenting milk causes at least partial hydrolysis of the lactose, so some people with lactose intolerance are still able to enjoy cheese, yogurt, or cooked foods containing milk. [11] Maltose is the two-unit member of the amylose homologous series, the key structural motif of starch. Under standard conditions, when 0.80 M ethanol and 1.2 M maltose were used as substrates with XgtA (2.5 units) and incubated in 30 mM HEPES-NaOH buffer (pH 8.0) at 45C, only one form of ethyl glucopyranoside was selectively obtained as a product. Today, we will go over the structure and stereochemistry of aldoses and ketoses with 4-7 carbon atoms. Most of the examined carbohydrates except nonreducing sugars were efficiency converted into ammonium formate under environment . contain two sugar units; and polysaccharides contain many Also, while they do contain small amounts of sugar, they also offer additional nutrients like fiber, vitamins and antioxidants. found as a component of lactose in milk. Learn the names of 56 different types of sugar, such as sucrose and agave nectar. Among these, the simplest monosaccharides are glyceraldehyde (an aldotriose) and dihydroxyacetone (a ketotriose). Complex carbohydrates like starch, glycogen, cellulose, and chitin are long polymers of monosaccharides. Carbohydrates (article) | Chemistry of life | Khan Academy The rest of the carbon atoms have hydroxyl groups attached to them, with the alcoholic groups present at each end of the backbone being primary alcohol groups. It is also found in many dental products. Aldoses, on the other hand, would also produce a red-colored product, but very slowly. Aldoses are also called polyhydroxy aldehydes. However, no research has investigated the effects of substituting fructose for maltose, and more research is needed. The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. All rights reserved. Fructose and all added sugars are major drivers of type 2 diabetes, according to a new analysis. Ketose b. Sucrose c. Maltose d. Aldose; Question: Name the following compound: a. Ketose b. Sucrose c. Maltose d. Aldose. Ketoses and aldoses can be chemically differentiated through Seliwanoff's test, where the sample is heated with acid and resorcinol. We tested for carotene, xanthophylls, chlorophyll A and B, and others . I would definitely recommend Study.com to my colleagues. Several structures are possible, but one example is shown. D) the ring form and the linear chain. How do I know if I have aldose or ketose? Maltose occurs to a limited extent in sprouting grain. carbons present. Maltose can easily be detected by the Woehlk test or Fearon's test on methylamine. High-Fructose Corn Syrup: Just Like Sugar, or Worse? People have long taken advantage of this natural process for food production. The sugars and proteins in malt are very nourishing for yeast, so malt has become important in brewing beer, whisky and malt vinegar. Evidence Shows Some Sugars Are Worse Than Others; Fructose Tops the List, The 56 Most Common Names for Sugar (Some Are Tricky). As with other sugars, when you consume maltose in moderation, your body uses it for energy and it does not cause harm (7, 8, 9). [4], Carbohydrates are generally divided into monosaccharides, oligosaccharides, and polysaccharides depending on the number of sugar subunits. The transketolase, which is in the pentose phosphate pathway, requires a coenzyme, thiamine pyrophosphate (TPP), to transfer a two-carbon unit from a ketose to an aldose. Another similarity between aldoses and ketoses is their ability to form cyclic ring structures in an acidic or basic medium, due to the reaction of the carbonyl group (aldehyde or ketone) with an interchain hydroxyl group. [9], Maltose is a malt component, a substance obtained when the grain is softened in water and germinates. [1], Lobry-de Bruyn-van Ekenstein transformation, https://en.wikipedia.org/w/index.php?title=Aldose&oldid=1137773946, This page was last edited on 6 February 2023, at 10:26. Since maltose is made up of just glucose, not fructose, it might be slightly healthier than table sugar. Glucose and galactose in milk: Milk produced by mammals contains the simple sugar Lactose, which is a disaccharide and is itself made up of two monosaccharides Glucose and Galactose, joined to each other via a glycosidic type of chemical bond. Ketoses can be differentiated from aldoses by Seliwanoffs test. The sucrose molecule is unique among the common disaccharides in having an -1,-2-glycosidic (head-to-head) linkage. Solution - Maltose is an aldose because it consists of two gluscoe molecules linked through an (14) glycosidic bond. Whether it occurs in the body or a glass beaker, the hydrolysis of maltose produces two molecules of D-glucose. The anomeric carbon (C1) of the second glucose molecule, which is not involved in a glycosidic bond, could be either an - or -anomer depending on the bond direction of the attached hydroxyl group relative to the CH2OH substituent of the same ring, resulting in either -maltose or -maltose. Structural Biochemistry/Carbohydrates/Ketoses - Wikibooks Selective and high-yield production of ethyl -d - PubMed Reactions of lactose & maltose. Monosaccharides which contain an aldehyde group are known as . Chemistry questions and answers. The D-glucose is more important than L-glucose as the biological systems have mechanisms to utilize D-glucose. Ketoses contain the ketone group - The major sugar Learn what the terms cured and uncured bacon actually mean when you see them in the store. The hexoses are divided into aldoses and ketoses according to whether they possess aldehydic or ketonic groups. Maltose: Good or Bad? - Healthline If a monosaccharide sugar consists of ketone as the carbonyl containing functional group is known as ketose. Glyceraldehyde is thus the simplest aldose and dihydroxyacetone is the simplest ketose. The same reactions can be carried out in the laboratory with dilute acid as a catalyst, although in that case the rate is much slower, and high temperatures are required. lessons in math, English, science, history, and more. Glucose is an aldohexose as it has six carbon atoms and an aldehyde group. The disaccharides differ from one another in their monosaccharide constituents and in the specific type of glycosidic linkage connecting them. Surface of various carbohydrates to ammonium formate was investigated in the existence in hydrogen peroxide and ammonium hydroxide. Maltose. The L- and D- forms of ketoses can be defined by the position of the hydroxyl group on the carbon backbone. Solved: Classify each of the following monosaccharides as an - Chegg Cyclic aldoses are usually drawn as Haworth projections, and open chain forms are commonly drawn as Fischer projections, both of which represent important stereochemical information about the forms they depict. Seliwanoff's Test- Definition, Principle, Procedure, Result, Uses Aldoses are compounds that contain an aldehydic functional group, while ketoses are compounds that contain a ketonic functional group. Learn aldose and ketose. This 1:1 mixture is referred to as invert sugar because it rotates plane-polarized light in the opposite direction than sucrose. The interconversion of an aldose to a ketose, such as D- glucose to D-fructose, occurs via their common enolate isomer. All monosaccharide ketoses are reducing sugars as they can be tautomerized into aldehyde, which then undergoes oxidation. Monosaccharide is a generic term that includes compounds with the general formula (CH2O)n, where n = 3 to 8. 25.6: Reactions of Monosaccharides - Chemistry LibreTexts Therefore, disaccharides are sugars composed of two monosaccharide units that are joined by a carbonoxygen-carbon linkage known as a glycosidic linkage. Maltose contain 2 aldose group & 0 ketose group. Plants store glucose as the polysaccharide starch. Carbohydrates - Classification - Elmhurst University This chemical difference is the main basis for distinguishing between these two classes of monosaccharides, chemically (Tollens reagent test, Seliwanoff's test, etc.). Glycogen There are a variety of interrelated classification schemes. Summary Carbohydrates are really just polyhydroxyaldehydes, the aldoses, or polyhydroxyketones, the ketoses. You can use aldoses such as glucose and galactose for energy, but you can also use non-aldose sugars -- called ketoses -- for the same purposes. Ketones are also called polyhydroxy ketones. Tetrose Definition and Examples - Biology Online Dictionary .mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}, Maltose (/mltos/[2] or /mltoz/[3]), also known as maltobiose or malt sugar, is a disaccharide formed from two units of glucose joined with an (14) bond. identify the products formed from the hydrolysis of a given disaccharide. Carbohydrates for the MCAT: Everything You Need to Know It is also present in highly variable quantities in partially hydrolyzed starch products like maltodextrin, corn syrup and acid-thinned starch. [2], Because they have at least one asymmetric carbon center, all aldoses exhibit stereoisomerism. From beginners to advanced. 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